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Molecular mass - Wikipedia, the free encyclopedia

Molecular mass

From Wikipedia, the free encyclopedia

The molecular mass (abbreviated Mr) of a substance, formerly also called molecular weight and abbreviated as MW, is the mass of one molecule of that substance, relative to the unified atomic mass unit u (equal to 1/12 the mass of one atom of carbon-12). Due to this relativity, the molecular mass of a substance is commonly referred to as the relative molecular mass, and abbreviated to Mr.

CONVERSION FACTOR of molecular mass to molar mass

molar mass = molecular mass * (6.022*10^23)

The molecular mass can be calculated as the sum of the atomic masses of all the atoms of any one molecule. The molecular mass can also be measured directly using mass spectrometry. In mass spectrometry, the molecular mass of a small molecule is usually reported as the monoisotopic mass, that is, the mass of the most common isotope of each element. The masses used to compute the monoisotopic molecular mass are found on a table of isotopic masses and are not the same as found on a typical periodic table. The average molecular mass is often used for larger molecules since molecules with many atoms are unlikely to be composed exclusively of the most abundant isotope of each element. This average mass can be calculated using the elemental mass numbers on a typical periodic table, since there is likely to be a statistical distribution of atoms representing the isotopes throughout the molecule.

The molar mass of a substance is the mass of 1 mol (the SI unit for the basis SI quantity amount of substance, having the symbol n). This has numerical value of the molecular mass multiplied by avagadro's constant 6.022*10^23, and the SI unit kg/mol, usually also found as stated in g/mol .

Example:
The atomic mass of hydrogen is 1.00784 u and that of oxygen is 15.9994 u;

therefore, the molecular mass of water with formula H2O is (2 × 1.00784 u) + 15.9994 u = 18.01508 u. Therefore, one mole of water has a mass of 18.0151 grams. However, the exact mass of hydrogen-1 (the most common isotope) is 1.00783, and the exact mass of oxygen-16 (the most common isotope) is 15.9949, so the mass of the most common single molecule of water is 18.0105 u.

Molecular mass or molar mass are used in stoichiometry calculations.

Since molecules are created by chemical reactions, not nuclear reactions, a molecule's molecular mass exactly equals the sum of the atomic masses of its constituent atoms.

The gram-molecular weight is the molecular weight of a chemical compound expressed in grams. Thus the molecular weight of calcium carbonate is 100 therefore the gram-molecular weight is 100 g. The Gram Molecular Weight is frequently used, particularly for calculating the concentration of solutions. Thus a molar solution will contain the gram molecular weight of a chemical dissolved to produce one litre of solution.

[edit] In polymer chemistry

In polymer chemistry, but unfortunately due to the varying chain lengths between the polymer macromolecules, various types of molar mass are used to quantify the molar mass distribution.

[edit] See also

[edit] External links

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